发明申请
- 专利标题: CATALYST COMPOSITION AND METHOD FOR PREPARING AMIDE USING THE SAME
- 专利标题(中): 催化剂组合物及其制备方法
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申请号: US13332834申请日: 2011-12-21
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公开(公告)号: US20120184733A1公开(公告)日: 2012-07-19
- 发明人: Tung-Han Tsai , Cheng-Fa Hsieh , Hung-Hung Hseuh , Chien-Chuan Shih
- 申请人: Tung-Han Tsai , Cheng-Fa Hsieh , Hung-Hung Hseuh , Chien-Chuan Shih
- 申请人地址: TW Taipei City
- 专利权人: China Petrochemical Development Corporation, Taipei (Taiwan)
- 当前专利权人: China Petrochemical Development Corporation, Taipei (Taiwan)
- 当前专利权人地址: TW Taipei City
- 优先权: TW100101602 20110117
- 主分类号: C07D201/04
- IPC分类号: C07D201/04 ; B01J31/02
摘要:
The present invention provides a method for preparing an amide. The method includes the steps of performing in a reactor including a catalyst composition having a nitrogen-containing heterocyclic compound and sulfuric acid Beckman rearrangement of a ketoxime to form a product stream having the amide, wherein a molar ratio of the nitrogen-containing heterocyclic compound to the sulfuric acid is from 1:1 to 1:8; and separating an organic phase having the amide and an aqueous phase having the catalyst composition from the product stream. The present invention facilitates the regeneration of the catalyst composition with low water content, so as to increase the conversion rate of a ketoxime and the selectivity of an amide.
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