发明申请
- 专利标题: Polymerization Process to Make Low Density Polyethylene
- 专利标题(中): 制备低密度聚乙烯的聚合方法
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申请号: US13515028申请日: 2010-12-14
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公开(公告)号: US20120252990A1公开(公告)日: 2012-10-04
- 发明人: Otto J. Berbee , Cornelis Den Doelder , Egbert Nijhof , Mehmet Demirors , Sjoerd A. De Vries
- 申请人: Otto J. Berbee , Cornelis Den Doelder , Egbert Nijhof , Mehmet Demirors , Sjoerd A. De Vries
- 国际申请: PCT/US2010/060244 WO 20101214
- 主分类号: C08F10/02
- IPC分类号: C08F10/02 ; C08F2/01
摘要:
A high pressure polymerization process to form an ethylene-based polymer comprises the steps of: A. Injecting a first feed comprising ethylene and optionally a chain transfer agent system (CTA system) into a first autoclave reactor zone operating at polymerization conditions to produce a first zone reaction product, the CTA system of the first reactor zone having a transfer activity Z1; and B. (1) Transferring at least part of the first zone reaction product to a second reactor zone selected from a second autoclave reactor zone or a tubular reactor zone and operating at polymerization conditions, and, optionally, (2) freshly injecting a second feed into the second reactor zone to produce a second zone reaction product, with the proviso that the second reactor zone contains a CTA system having a transfer activity Z2; and with the proviso that the ratio of Z1/Z2 is less than 1.
公开/授权文献
- US08729186B2 Polymerization process to make low density polyethylene 公开/授权日:2014-05-20
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