发明申请
US20120253050A1 SYNTHESIS OF 8-AMINO BORON DIPYRROMETHENES HAVING BLUE FLUORESCENCE 有权
具有蓝色荧光的8-氨基硼烷二氯甲烷的合成

SYNTHESIS OF 8-AMINO BORON DIPYRROMETHENES HAVING BLUE FLUORESCENCE
摘要:
A family of six 8-amino boron dipyrromethenes having Formulas 1, 2, 3, 4, 6, and 7 has been prepared. The presence of the amine group alters the emission properties of the boron dipyrromethene, such that these compounds are characterized by unexpected blue fluorescence, providing for potential use as lasers. The compound having formula 1 has very high quantum yield. The 8-amino boron dipyrromethenes are prepared in a straightforward, high yield synthesis by substituting an amine group for the thiomethyl group at the 8 position in 8-thiomethyl boron dipyrromethene. The compounds having Formulas 6 and 7 may be used to incorporate peptides and proteins, thus providing biomolecules marked with fluorescent fragments.
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