发明申请
- 专利标题: Method for Manufacturing Fluoropolymers
- 专利标题(中): 氟聚合物的制造方法
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申请号: US13515973申请日: 2010-12-16
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公开(公告)号: US20120283383A1公开(公告)日: 2012-11-08
- 发明人: Riccardo Pieri , Valeri Kapeliouchko , Liubov Chernysheva
- 申请人: Riccardo Pieri , Valeri Kapeliouchko , Liubov Chernysheva
- 申请人地址: IT Bollate MI
- 专利权人: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.
- 当前专利权人: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.
- 当前专利权人地址: IT Bollate MI
- 优先权: EP09179997.3 20091218
- 国际申请: PCT/EP2010/069955 WO 20101216
- 主分类号: C08L27/18
- IPC分类号: C08L27/18 ; C07C51/42 ; C08K5/06 ; C09K3/00
摘要:
The invention pertains to a process for manufacturing a (per)fluoropolymer, said process comprising polymerizing one or more fluorinated monomers in the presence of a multi-phase medium, said medium comprising: (A) a water phase [phase (W)]; (B) at least one fluorinated surfactant [surfactant (FS)] having formula (I) here below: Rf—(OCF2CF2)k-1—O—CF2—COOXa (I) wherein Rf is a C1-C3 perfluoroalkyl group comprising, optionally, one or more ether oxygen atoms, k is 2 or 3 and Xa is a selected from a monovalent metal and an ammonium group of formula NRN4, wherein RN, equal or different at each occurrence, is a hydrogen atom or a C1-C3 alkyl group; (C) an oil phase [phase (O)] comprising: at least one non-functional (per)fluoropolyether (non-functional PFPE) comprising at least one (per)fluoropolyoxyalkylene chain [chain (RF)] and at least one functional (per)fluoropolyether (functional PFPE) comprising at least one (per)fluoropolyoxyalkylene chain [chain (R′F)] and having a number average molecular weight of at least 1000 and a solubility of less than 1% by weight in water at 25° C.
公开/授权文献
- US09803036B2 Method for manufacturing fluoropolymers 公开/授权日:2017-10-31