Disclosed is a battery cooling structure for an environmental-friendly vehicle. The battery cooling structure for the environmental-friendly vehicle includes a plurality of battery packs that supply power to a motor and are arranged in parallel so as to be spaced a predetermined distance from each other inside a tire well. An inflow duct is disposed to provide fluid communication and connection with the interior of the vehicle so that the air inside the vehicle is sucked into the inflow duct. A plurality of diverging ducts independently supply the air to the respective battery packs which are arranged and spaced a predetermined distance from each other on the downstream side of the inflow duct. A lower duct is disposed under the battery pack and joins diverging air flows, and a cooling fan is disposed on downstream side of the lower duct and is configured to discharge the air to the outside.