发明申请
- 专利标题: CATALYST FOR GLYCERIN DEHYDRATION, AND PROCESS FOR PRODUCING ACROLEIN, PROCESS FOR PRODUCING ACRYLIC ACID, AND PROCESS FOR PRODUCING HYDROPHILIC RESIN EACH USING THE CATALYST
- 专利标题(中): 甘油脱水用催化剂及其制备方法,丙烯酸生产方法以及使用催化剂生产氢化树脂的方法
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申请号: US13582521申请日: 2011-03-28
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公开(公告)号: US20130018161A1公开(公告)日: 2013-01-17
- 发明人: Takayuki Ezawa , Masaki Okada , Yoshitaka Arita
- 申请人: Takayuki Ezawa , Masaki Okada , Yoshitaka Arita
- 优先权: JP2010-084562 20100331; JP2010-084563 20100331; JP2010-212527 20100922; JP2010-212528 20100922; JP2010-222801 20100930; JP2010-222802 20100930
- 国际申请: PCT/JP2011/057700 WO 20110328
- 主分类号: B01J27/14
- IPC分类号: B01J27/14 ; C08F20/06 ; C07C45/00 ; C07C51/235 ; B01J27/18 ; B01J27/185
摘要:
A catalyst for glycerin dehydration of the present invention comprises boron phosphate or a rare-earth metal phosphate, wherein a molar ratio P/B of phosphorus (P) to boron (B) or a molar ratio P/R of phosphorus (P) to a rare-earth metal (R) is more than 1.0 and 2.0 or less. An another catalyst for glycerin dehydration of the present invention comprises a combination of boron phosphate and a metal element or a combination of a rare-earth metal phosphate and a metal element other than a rare-earth metal, wherein a molar ratio M/(P+B) of a metal element (M) to phosphorus (P) and boron (B) or a molar ratio M/(P+R) of a metal element (M) to phosphorus (P) and a rare-earth metal (R) is more than 0.00005 and 0.5 or less.
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