The present disclosure relates to methods for producing hydrogen using photosynthetic bacteria comprising a step of culturing the photosynthetic bacteria in the presence of alcohol at the condition under which the photosynthesis occurs. The present methods are cost-effective and have a high applicability due to the increased hydrogen productivity compared to the conventional methods in addition to not being sensitive by the inhibitory action by ammonium ion present in the culture. Thus the present methods are particularly useful for producing hydrogen using organic wastes which contains large amount of ammonia therein.