发明申请
- 专利标题: Method for Preparing 1-Octene by Oligomerization of Ethylene
- 专利标题(中): 乙烯低聚制备1-辛烯的方法
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申请号: US13704961申请日: 2011-06-03
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公开(公告)号: US20130090508A1公开(公告)日: 2013-04-11
- 发明人: Gang Wang , Baojun Zhang , Jianzhong Li , Sihan Wang , Jiabo Qu , Defu He , Guizhi Wang , Qian Chen , Buwei Yu , Deshun Zhang , Libo Wang , Yali Wang , Liwei Liang , Yuxin Gao , Jie Li , Wenchao Zhang , Hua Li , Xiaoyu Gao , Shouhui Zha , Fuling Huang , Jing Wei , Xiuhui Wang , Xiangmin Yu , Jingying Zhao , Xuemei Han , Chunfeng Song , Junfeng Wei , Rui Meng
- 申请人: Gang Wang , Baojun Zhang , Jianzhong Li , Sihan Wang , Jiabo Qu , Defu He , Guizhi Wang , Qian Chen , Buwei Yu , Deshun Zhang , Libo Wang , Yali Wang , Liwei Liang , Yuxin Gao , Jie Li , Wenchao Zhang , Hua Li , Xiaoyu Gao , Shouhui Zha , Fuling Huang , Jing Wei , Xiuhui Wang , Xiangmin Yu , Jingying Zhao , Xuemei Han , Chunfeng Song , Junfeng Wei , Rui Meng
- 申请人地址: CN Beijing
- 专利权人: PETROCHINA COMPANY LIMITED
- 当前专利权人: PETROCHINA COMPANY LIMITED
- 当前专利权人地址: CN Beijing
- 优先权: CN201010543099.1 20101111
- 国际申请: PCT/CN2011/000945 WO 20110603
- 主分类号: C07C2/30
- IPC分类号: C07C2/30
摘要:
Disclosed is a method for preparing 1-octene in the presence of a catalyst system for ethylene oligomerization, which includes: premixing a part of ethylene gas as raw material with a solvent, mixing with the components a+b, c and d of the catalyst system, and then sending in a reactor; directly sending the rest of ethylene gas in the reactor; discharging the resultant liquid from the upper part of the reactor into an overflow channel; adding a catalysis stopping agent to the overflow channel; and then separating the resultant liquid. The advantages of the method are high selectivity of 1-octene and high catalytic activity.