发明申请
US20130096272A1 PROCESS FOR PREPARING A (METH)ACRYLATE COPOLYMER CONTAINING TERTIARY AMINO GROUPS BY FREE-RADICAL POLYMERIZATION IN SOLUTION
有权
通过溶液中的自由基聚合制备含有仲胺基团的(甲基)丙烯酸酯共聚物的方法
- 专利标题: PROCESS FOR PREPARING A (METH)ACRYLATE COPOLYMER CONTAINING TERTIARY AMINO GROUPS BY FREE-RADICAL POLYMERIZATION IN SOLUTION
- 专利标题(中): 通过溶液中的自由基聚合制备含有仲胺基团的(甲基)丙烯酸酯共聚物的方法
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申请号: US13805523申请日: 2010-10-13
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公开(公告)号: US20130096272A1公开(公告)日: 2013-04-18
- 发明人: Christian Meier , Andreas Weber , Johannes Vorholz , Alpertunga Kueksal , Andreas Klosendorf , Pamela Boehmann , Marcus Denger , Norbert Hoffmann , Nikolaos Papadopoulos
- 申请人: Christian Meier , Andreas Weber , Johannes Vorholz , Alpertunga Kueksal , Andreas Klosendorf , Pamela Boehmann , Marcus Denger , Norbert Hoffmann , Nikolaos Papadopoulos
- 申请人地址: DE Darmstadt
- 专利权人: Evonik Roehm GmbH
- 当前专利权人: Evonik Roehm GmbH
- 当前专利权人地址: DE Darmstadt
- 国际申请: PCT/EP2010/065333 WO 20101013
- 主分类号: C08F2/06
- IPC分类号: C08F2/06
摘要:
The invention relates to a process for preparing a (meth)acrylate copolymer containing quaternary ammonium groups from a monomer mixture selected from: (a) 80 to 99% by weight of a C1-C4-alkyl ester of acrylic acid or methacrylic acid; and (b) 20 to 1% by weight of an alkyl ester of acrylic acid or methacrylic acid with a quaternary ammonium group in the alkyl radical; and (c) 0 to 10% of further copolymerizable vinyl monomers whereby one or more polymerization initiators, optionally one or more molecular weight regulators and one or more solvents or of a solvent mixture are added to the monomer mixture to give a polymerization mixture, which is polymerized at temperatures from 30 to 120 C over a period of 2 to 24 hours, where the polymerization mixture is polymerized to a polymerization syrup with a conversion of the monomers to the copolymer of at least 99% by weight, where the polymerization syrup is subsequently degassed by distillation or by extrusion and the degassed polymerization syrup is further comminuted to a copolymer preparation in the form of a granulate or powder and where the copolymer preparation is characterized by a molecular weight (Mw) of 25.000 to 50.000, a polydispersity index of 2.0 to 3.0 and a residual solvent concentration of less than 10.000 ppm by weight.
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