发明申请
- 专利标题: Integrated Acid and Alcohol Production Process
- 专利标题(中): 综合酸和酒精生产过程
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申请号: US13292802申请日: 2011-11-09
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公开(公告)号: US20130116476A1公开(公告)日: 2013-05-09
- 发明人: David Lee , Lincoln Sarager , Mark O. Scates , Ronald D. Shaver , James H. Zink , Raymond J. Zinobile
- 申请人: David Lee , Lincoln Sarager , Mark O. Scates , Ronald D. Shaver , James H. Zink , Raymond J. Zinobile
- 申请人地址: US TX Dallas
- 专利权人: Celanese International Corporation
- 当前专利权人: Celanese International Corporation
- 当前专利权人地址: US TX Dallas
- 主分类号: C07C29/74
- IPC分类号: C07C29/74 ; C07C29/80
摘要:
An integrated process for producing ethanol, comprising the step of reacting carbon monoxide with at least one reactant in a reactor containing a reaction medium to produce a liquid reaction product comprising acetic acid. The reaction medium comprises water, acetic acid, methyl acetate, a halogen promoter, and a first catalyst. The process further comprises the steps of directly feeding the liquid reaction product from the reactor to a distillation column and withdrawing from it an overhead stream comprising methyl acetate, and/or halogen promoter, a bottoms stream comprising a solution of the first catalyst, and a liquid acetic acid sidestream; and hydrogenating acetic acid of the liquid acetic acid sidestream in the presence of a second catalyst and under conditions effective to form a crude ethanol product comprising ethanol and water. No flashing vessel is used to purify the liquid reaction product. Ethanol is recovered from the crude ethanol product.
公开/授权文献
- US08614359B2 Integrated acid and alcohol production process 公开/授权日:2013-12-24
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