发明申请
- 专利标题: NEGATIVE ELECTRODE FOR NON-AQUEOUS SECONDARY BATTERY, AND A NON-AQUEOUS SECONDARY BATTERY
- 专利标题(中): 非水性二次电池负极和非水性二次电池
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申请号: US13814069申请日: 2011-08-03
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公开(公告)号: US20130136988A1公开(公告)日: 2013-05-30
- 发明人: Naokage Tanaka , Akira Inaba , Keiichiro Uenae , Masayuki Yamada , Kazunobu Matsumoto
- 申请人: Naokage Tanaka , Akira Inaba , Keiichiro Uenae , Masayuki Yamada , Kazunobu Matsumoto
- 申请人地址: JP Otokuni-gun, Kyoto
- 专利权人: HITACHI MAXELL ENERGY, LTD.
- 当前专利权人: HITACHI MAXELL ENERGY, LTD.
- 当前专利权人地址: JP Otokuni-gun, Kyoto
- 优先权: JP2010-174270 20100803
- 国际申请: PCT/JP2011/067731 WO 20110803
- 主分类号: H01M4/131
- IPC分类号: H01M4/131 ; H01M4/134 ; H01M4/133
摘要:
[Objectives] The present invention provides a non-aqueous secondary battery in which a material containing Si and O as constituent elements is used in a negative electrode. The present invention provides a non-aqueous secondary battery having good charge discharge cycle characteristics, and suppressing the battery swelling associated with the charge and the discharge. Also, the present invention relates to a negative electrode that can provide the non-aqueous secondary battery. [Solution] The negative electrode includes a negative electrode active material, including a composite of a material containing Si and O as constitution elements (atom ratio x of O to Si is 0.5≦x≦1.5) in combination with a carbon material, and graphite. The graphite has an average particle diameter dg(μm) of 4 to 20 μm. The material containing Si and O as constitution elements has an average particle diameter ds(μm) of 1 μm or more. The ratio ds/dg (i.e., ds to dg) is 0.05 to 1. The material containing Si and O as constitution elements has a crystallite diameter of 50 nm or less, the crystallite diameter is calculated from a half width at a (220) plane of Si obtained by an X-ray diffraction method, using Scherrer Formula. In 100 mass % of the composite of the material containing Si and O as constitution elements, and the carbon material, a ratio of the material containing Si and O as constitution elements is 70 to 95 mass %.
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