发明申请
US20130261345A1 PRODUCTION OF FUEL ADDITIVES VIA SIMULTANEOUS DEHYDRATION AND SKELETAL ISOMERISATION OF ISOBUTANOL ON ACID CATALYSTS FOLLOWED BY ETHERIFICATION 审中-公开
通过醚化在酸性催化剂上通过同时脱水和异构异构体来生产燃料添加剂

  • 专利标题: PRODUCTION OF FUEL ADDITIVES VIA SIMULTANEOUS DEHYDRATION AND SKELETAL ISOMERISATION OF ISOBUTANOL ON ACID CATALYSTS FOLLOWED BY ETHERIFICATION
  • 专利标题(中): 通过醚化在酸性催化剂上通过同时脱水和异构异构体来生产燃料添加剂
  • 申请号: US13878016
    申请日: 2011-12-20
  • 公开(公告)号: US20130261345A1
    公开(公告)日: 2013-10-03
  • 发明人: Cindy AdamDelphine MinouxNikolaï Nesterenko
  • 申请人: Cindy AdamDelphine MinouxNikolaï Nesterenko
  • 申请人地址: FR PUTEAUX
  • 专利权人: TOTAL RAFFINAGE MARKETING
  • 当前专利权人: TOTAL RAFFINAGE MARKETING
  • 当前专利权人地址: FR PUTEAUX
  • 优先权: FR1060911 20101221
  • 国际申请: PCT/EP2011/073413 WO 20111220
  • 主分类号: C10L1/185
  • IPC分类号: C10L1/185
PRODUCTION OF FUEL ADDITIVES VIA SIMULTANEOUS DEHYDRATION AND SKELETAL ISOMERISATION OF ISOBUTANOL ON ACID CATALYSTS FOLLOWED BY ETHERIFICATION
摘要:
The present invention relates to a process for the production of fuel additives in which in a first step isobutanol is subjected to a simultaneous dehydration and skeletal isomerisation to make substantially corresponding olefins, having the same number of carbons and consisting essentially of a mixture of n-butenes and iso-butene and in a second step the butene mixture is subjected to etherification, said process comprising: a) introducing in at least one reactor a stream (A) comprising at least 40 wt % isobutanol, optionally an inert component, b) contacting said stream with at least one catalyst in said reactor(s) at conditions effective to simultaneously dehydrate and skeletal isomerise at least a portion of the isobutanol to make a mixture of n-butenes and iso-butene, c) removing the inert component if any, recovering from said reactor(s) a stream (B) comprising a mixture of n-butenes and iso-butene, d) sending the stream (B) to at least one etherification reactor and contacting stream (B) with at least one catalyst in said etherification reactor(s), in the presence of ethanol and/or methanol, at conditions effective to produce ETBE and/or MTBE respectively, e) recovering from said etherification reactor a stream (E) comprising essentially ETBE and/or MTBE, unreacted butenes, heavies, optionally unreacted ethanol and/or methanol respectively, f) fractionating stream (E) to recover ETBE and/or MTBE.
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