A method for mineral analysis of a sample based on detection of NQR and/or Local Field Magnetic Resonance (LFMR) signals from a particular substance within a sample includes: setting a frequency of RF pulses to be approximately equal to one of the NQR or LFMR frequencies of the substance; setting a set of parameters of the RF pulses to be optimal for the substance; setting a set of receiving parameters to be optimal for the substance; tuning the probe to maximum sensitivity for the signals detected at predetermined frequency and/or to maximum power transfer efficiency for RF pulses transmitted with the probe; transmitting the RF pulses with the probe at said optimal level during a transmitting period to irradiate the sample and excite an NQR or LFMR signal in the substance, if present; detecting and processing NQR or LFMR signals emitted by the substance; and calculating the concentration of the substance in the sample.