A material information detection apparatus, a phantom information recording apparatus, and operation methods for the apparatuses are provided. The material information detection apparatus includes a database configured to store phantom information obtained by projecting a multi-energy X-rayon a phantom comprising a plurality of materials, an input device configured to receive a plurality of pieces of object information per energy level, the object information obtained by projecting a multi-energy X-ray on an analysis object, and a detector configured to detect information related to materials constituting the analysis object based on the phantom information and the plurality of pieces of object information per energy level.