A two-core optical fiber is provided for use in Brillouin distributed fiber sensor applications and systems. The two-core fiber includes a first and second core. Each core is configured to exhibit a Brillouin frequency shift greater than 30 Mhz relative to the other core. Further, each core possesses temperature and strain coefficients that differ from the other core. The cores can be configured to produce Brillouin frequency shift levels of at least 30 Mhz relative to one another. These differences in shift levels may be effected by adjustment of the material compositions, doping concentrations and/or refractive index profiles of each of the cores. These optical fibers may also be used in BOTDR- and BOTDA-based sensor systems and arrangements.