A system and a process for recovering bitumen from oil sands are provided. The system includes a bitumen solvent comprised of at least 75 mol % dimethyl sulfide that is first contact miscible with bitumen, an oil sands material comprised of bitumen, and a contacting apparatus configured to receive the bitumen solvent and the oil sands material and to contact and mix the bitumen solvent and oil sands material to form a bitumen-containing extract and a bitumen-depleted oil sands material. The process includes the steps of providing the oil sands material; contacting the oil sands material with the solvent comprised of at least 75 mol % dimethyl sulfide to form the bitumen-containing extract and the bitumen-depleted oil sands material; and separating the bitumen-containing extract from the bitumen-depleted oil sands material.