发明申请
US20140275657A1 METHOD FOR PRODUCING CHLOROHYDROCARBON HAVING CONJUGATED DOUBLE BONDS 有权
用于生产具有结合双重骨架的氯硅橡胶的方法

METHOD FOR PRODUCING CHLOROHYDROCARBON HAVING CONJUGATED DOUBLE BONDS
摘要:
Provided is a method for producing a chlorohydrocarbon having conjugated double bonds by stereoselectively chlorinating an alcohol having conjugated double bonds. More specifically, provided is a method for producing a chlorohydrocarbon having conjugated double bonds, the method including a step of chlorinating an alcohol having conjugated double bonds with a chlorinating agent in a solvent in the presence of a base and in the absence of metal salt for chlorination of the alcohol, and the alcohol being represented by the formula (1): RCH═CHCH═CH—Z—OH  (1) wherein R represents a hydrogen atom or a linear, branched or cyclic C1-17 monovalent hydrocarbon group which may have at least one double bond or at least one triple bond; and Z represents a linear, branched or cyclic C1-17 divalent hydrocarbon group which may have at least one double bond or at least one triple bond.
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