Invention Application
US20140296469A1 CONTINUOUS PRODUCTION METHOD FOR POLYCARBONATE-POLYORGANOSILOXANE COPOLYMER
有权
聚碳酸酯 - 聚硅氧烷共聚物的连续生产方法
- Patent Title: CONTINUOUS PRODUCTION METHOD FOR POLYCARBONATE-POLYORGANOSILOXANE COPOLYMER
- Patent Title (中): 聚碳酸酯 - 聚硅氧烷共聚物的连续生产方法
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Application No.: US14362375Application Date: 2012-11-16
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Publication No.: US20140296469A1Publication Date: 2014-10-02
- Inventor: Yasuhiro Ishikawa , Hiroaki Motegi , Yukiko Nagao
- Applicant: IDEMITSU KOSAN CO., LTD.
- Applicant Address: JP Chiyoda-ku, Tokyo
- Assignee: IDEMITSU KOSAN CO., LTD.
- Current Assignee: IDEMITSU KOSAN CO., LTD.
- Current Assignee Address: JP Chiyoda-ku, Tokyo
- Priority: JP2011-265163 20111202
- International Application: PCT/JP2012/079854 WO 20121116
- Main IPC: C08G64/06
- IPC: C08G64/06

Abstract:
The present invention provides a method for producing a polycarbonate-polyorganosiloxane copolymer economically and stably, in particular, the present invention is concerned with a method for continuous production of a polycarbonate-polyorganosiloxane copolymer including (A) a step of withdrawing a polymerization reaction solution obtained by polymerizing a dihydric phenol compound, a carbonate precursor, and a polyorganosiloxane in the presence of an alkaline compound aqueous solution and a water-insoluble organic solvent continuously or intermittently from a reactor; (B) a step of separating the polymerization reaction solution withdrawn in the step (A) into an aqueous phase and a water-insoluble organic solvent phase; and (C) a step of after washing the water-insoluble organic solvent phase separated in the step (B) with an acidic aqueous solution, separating the resultant into an aqueous phase and a water-insoluble organic solvent phase, wherein the aqueous phase separated in the step (C) is extracted with a water-insoluble organic solvent, the content of the polycarbonate-polyorganosiloxane copolymer in the obtained extract is controlled to not more than 2% by mass, and a part or the whole of the extract is reused for the step (A).
Public/Granted literature
- US09045586B2 Continuous production method for polycarbonate-polyorganosiloxane copolymer Public/Granted day:2015-06-02
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