Invention Application
US20140316085A1 Process of Producing Polyolefins Using Metallocene Polymerization Catalysts and Copolymers Therefrom 有权
使用茂金属聚合催化剂和共聚物生产聚烯烃的方法

Process of Producing Polyolefins Using Metallocene Polymerization Catalysts and Copolymers Therefrom
Abstract:
An ethylene copolymer, a Group 4 transition metal catalyst compound, and methods for polymerization using such a compound, said compound represented by the formula: (L)p(R′)zT(Cp)(A)MX2, where M is a Group 4 metal; z is 0 to 8; p is 1 to 3; X is an anionic leaving group; T is a bridging group; R1 to R4 are hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, aryl group, substituted aryl group, or a heteroatom-containing group (where adjacent R groups can form rings); R′ is hydrogen, a C1 to C10 alkyl group, a C6 to C24 aryl group, or a C7 to C40 alkylaryl group; and L is a heteroatom or heteroatom-containing group bound to T, Cp is a cyclopentadienyl ring substituted with 0 to 4 substituent groups (where adjacent groups can form C4 to C20 rings); A is Cp or (JS′z*-1-y), where J is a Group 15 or 16 element; S′ is a hydrocarbyl, substituted hydrocarbyl, or heteroatom; z* is 2 or 3, and y is 0 or 1, is provided.
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