发明申请
US20140316097A1 METHOD AND APPARATUS FOR RECOVERING LACTIDE FROM POLYLACTIDE OR GLYCOLIDE FROM POLYGLYCOLIDE
审中-公开
从聚异氰酸酯从聚酰胺或甘油中回收柠檬酸的方法和装置
- 专利标题: METHOD AND APPARATUS FOR RECOVERING LACTIDE FROM POLYLACTIDE OR GLYCOLIDE FROM POLYGLYCOLIDE
- 专利标题(中): 从聚异氰酸酯从聚酰胺或甘油中回收柠檬酸的方法和装置
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申请号: US14238800申请日: 2012-08-17
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公开(公告)号: US20140316097A1公开(公告)日: 2014-10-23
- 发明人: Rainer Hagen
- 申请人: Rainer Hagen
- 申请人地址: DE Berlin
- 专利权人: UHDE INVENTA-FISCHER GMBH
- 当前专利权人: UHDE INVENTA-FISCHER GMBH
- 当前专利权人地址: DE Berlin
- 优先权: EP11006825.1 20110819
- 国际申请: PCT/EP2012/066065 WO 20120817
- 主分类号: C07D319/12
- IPC分类号: C07D319/12 ; C08G63/08
摘要:
The present invention relates to a process for recovering lactide from polylactide (PLA) or glycolide from polyglycolide (PGA), in which, in a first step, PLA or PGA is contacted with a hydrolysing medium and hydrolytically degraded to oligomers. In a further step, a cyclising depolymerisation of the oligomers obtained in the first step is effected to give lactide or glycolide. In addition, the present invention relates to an apparatus based on the combination of a hydrolysis apparatus with a depolymerisation reactor, with which the above-described process can be performed. The core of the process according to the invention is a partial hydrolysis of the polymeric materials originally used in combination with a cyclising depolymerisation.
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