The present invention relates to a novel secondary structure of carbon nanostructures, a bundle thereof and a composite comprising the same. The secondary structure according to the present invention is characterized that it is formed by a plurality of carbon nanostructures (CNSs) assembled to have a tube form in whole or in part.The novel secondary structure according to the present invention, the bundle thereof and the composite comprising the same are highly applicable in fields of energy materials, functional composites, batteries, semiconductors and the like.