发明申请
- 专利标题: Method For In-Situ Synthesis Of Silicon Nanoparticles
- 专利标题(中): 硅纳米粒子的原位合成方法
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申请号: US14379677申请日: 2013-02-20
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公开(公告)号: US20150031794A1公开(公告)日: 2015-01-29
- 发明人: Chloé Schubert , Olivier Poncelet
- 申请人: Commissariat A L'Energie Atomique Et Aux Energies Alternative
- 优先权: FR1251606 20120222
- 国际申请: PCT/IB2013/051371 WO 20130220
- 主分类号: C08J3/215
- IPC分类号: C08J3/215 ; H01B3/40 ; H01B3/30 ; C08K7/26 ; H01B3/42
摘要:
The invention relates to a method for in-situ synthesis of silicon nanoparticles in a thermosetting polymeric matrix, the thermosetting and thermoset matrices obtained in this way and a material including same. The method includes the following steps: a) forming an aqueous-phase/organic-phase inverse emulsion, wherein the aqueous phase includes at least a basic catalyst and the organic phase includes at least a non-cross-linked (co)polymer precursor chosen from an aliphatic, cycloaliphatic or aromatic epoxy resin precursor, a polyester-imide precursor, an unsaturated/epoxy polyester (co)polymer precursor, a polyether/epoxy (co)polymer precursor and a polyurethane precursor; b) introducing, into the inverse emulsion formed in step a), at least one silicon precursor forming a complete network whereof the rate of hydrolysis is greater than the cross-linking speed of the (co)polymer and c) stirring the mixture obtained in step b) and heating to a temperature between 20° C. and 70° C.
公开/授权文献
- US09617396B2 Method for in-situ synthesis of silicon nanoparticles 公开/授权日:2017-04-11