An operations fluid is provided for treatment operations on wellbores associated with hydrocarbon production, the operations fluid comprising: water, an inorganic primary acid; and an alkyl acid surfactant. The alkyl acid surfactant has the general formula {R—X}, wherein R comprises at least one of linear and branched alkyl and alkyl aryl hydrocarbon chains and X comprises an acid, and X may comprise an acid selected from the group comprising sulfonic acids, carboxylic acids, phosphoric acids, and mixtures thereof. The alkyl acid may include an acid selected from the group consisting of alkyl or alkyl aryl acids. The operations fluid may be useful in treatment operations related to formation stimulation or mitigation of non-aqueous filter cakes (NAF) and/or formation invasion by NAF drilling fluids.