A multilayer structure having at least two different print materials pattern is formed on a receiver element using an elastomeric relief element having a relief pattern. Multiple different printable material compositions are sequentially applied only to the uppermost relief surface of the elastomeric relief element and at least at least 50 weight % of a carrier liquid is removed from each printable material composition. During contact of the multilayer structure on the uppermost relief surface and the receiver element, the elastomeric relief element is compressed by at least 10 μm of its original thickness. The elastomeric relief element is then separated from the receiver element to leave a pattern of the multilayer structure on the receiver element, wherein at least 70 weight % of the multiple print materials is transferred to the receiver element.