A cellulose acylate film, containing: at least two or more of chelating agents having different pKa values from one another, wherein the chelating agents comprise: a chelating agent A having at least one functional group whose acid dissociation constant pKa, measured at 25° C. in a mixed solvent having a mixing ratio of tetrahydrofuran 60 ml/water 40 ml, is 6 or less; and a chelating agent B having at least one functional group of a conjugate acid whose pKa, measured at the same condition, is 7 or more; and a cellulose acylate, and wherein the number of bright spots of the cellulose acylate film is equal to or less than 500/cm2; a polarizing plate protective film, a polarizing plate and a liquid crystal display using the same.