发明申请
- 专利标题: METHOD FOR PRODUCING METHACROLEIN AND METHACRYLIC ACID
- 专利标题(中): 生产甲基纤维素和甲基丙烯酸的方法
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申请号: US14432923申请日: 2013-10-29
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公开(公告)号: US20150274626A1公开(公告)日: 2015-10-01
- 发明人: Tetsufumi Yamaguchi , Tomomasa Tatsumi , Masahide Kondo , Yuji Fujimori
- 申请人: MITSUBISHI RAYON CO.,LTD.
- 申请人地址: JP Chiyoda-ku, Tokyo
- 专利权人: MITSUBISHI RAYON CO.,LTD.
- 当前专利权人: MITSUBISHI RAYON CO.,LTD.
- 当前专利权人地址: JP Chiyoda-ku, Tokyo
- 优先权: JP2012-245263 20121107
- 国际申请: PCT/JP2013/079250 WO 20131029
- 主分类号: C07C45/35
- IPC分类号: C07C45/35 ; C07C51/25
摘要:
Provided is a method for producing methacrolein and methacrylic acid which can improve yields of methacrolein and methacrylic acid. The method is to produce methacrolein and methacrylic acid through gas-phase contact oxidation of at least one raw material selected from the group consisting of isobutylene, TBA, and MTBE with molecular oxygen in the presence of a catalyst containing molybdenum, bismuth, and iron, using a fixed-bed reactor, in which, when a boundary temperature of activation energy of the oxidation reaction is denoted by TA (° C.), the reaction is started at a temperature lower than the reaction temperature TA (° C.), the reaction is controlled while increasing a reaction temperature such that a reaction rate of the raw material is kept constant, and the reaction is ended at a reaction temperature exceeding TA (° C.), and, when an average of rates of temperature increase until the reaction temperature reaches TA (° C.) is denoted by A (° C./hr) and an average of rates of temperature increase in the reaction temperature exceeding TA (° C.) is denoted by B (° C./hr), a ratio (A/B) of A and B is 0.05 to 0.18.
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