A 12 volt automotive battery system includes a first battery coupled to an electrical system, and the first battery includes a first battery chemistry. Further, the 12 volt automotive battery system includes a second battery coupled in parallel with the first battery and selectively coupled to the electrical system via a bi-stable relay. The second battery includes a second battery chemistry that has a higher coulombic efficiency than the first battery chemistry. Additionally, the bi-stable relay couples the second battery to the electrical system during regenerative braking to enable the second battery to capture a majority of the power generated during regenerative braking. Furthermore, the bi-stable relay maintains a coupling of the second battery to the electrical system when the vehicle transitions from a key-on position to a key-off position.