发明申请
US20160108156A1 MOLECULAR WEIGHT CONTROL OF POLYOLEFINS USING HALOGENATED BIS-PHENYLPHENOXY CATALYSTS
有权
使用氢化双 - 苯基氧化催化剂的聚烯烃的分子量控制
- 专利标题: MOLECULAR WEIGHT CONTROL OF POLYOLEFINS USING HALOGENATED BIS-PHENYLPHENOXY CATALYSTS
- 专利标题(中): 使用氢化双 - 苯基氧化催化剂的聚烯烃的分子量控制
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申请号: US14781419申请日: 2014-06-26
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公开(公告)号: US20160108156A1公开(公告)日: 2016-04-21
- 发明人: Jerzy Klosin , Ruth Figueroa , Robert DJ Froese
- 申请人: DOW GLOBAL TECHNOLOGIES LLC
- 国际申请: PCT/US2014/044374 WO 20140626
- 主分类号: C08F210/16
- IPC分类号: C08F210/16
摘要:
A process for preparing an olefin homopolymer or copolymer comprises contacting ethylene, an alpha-olefin, or a combination, and a catalytic amount of a metal-ligand complex catalyst of a particular formula that requires at least one halogen atom that is ortho to a bridging moiety. The strategic location of the halogen atom(s) ensures a product having a molecular weight that is predictably and significantly reduced in comparison with that of copolymers produced using otherwise identical metal-ligand complex catalysts that lack halogen atoms at the specified sites.
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