发明申请
US20160108156A1 MOLECULAR WEIGHT CONTROL OF POLYOLEFINS USING HALOGENATED BIS-PHENYLPHENOXY CATALYSTS 有权
使用氢化双 - 苯基氧化催化剂的聚烯烃的分子量控制

  • 专利标题: MOLECULAR WEIGHT CONTROL OF POLYOLEFINS USING HALOGENATED BIS-PHENYLPHENOXY CATALYSTS
  • 专利标题(中): 使用氢化双 - 苯基氧化催化剂的聚烯烃的分子量控制
  • 申请号: US14781419
    申请日: 2014-06-26
  • 公开(公告)号: US20160108156A1
    公开(公告)日: 2016-04-21
  • 发明人: Jerzy KlosinRuth FigueroaRobert DJ Froese
  • 申请人: DOW GLOBAL TECHNOLOGIES LLC
  • 国际申请: PCT/US2014/044374 WO 20140626
  • 主分类号: C08F210/16
  • IPC分类号: C08F210/16
MOLECULAR WEIGHT CONTROL OF POLYOLEFINS USING HALOGENATED BIS-PHENYLPHENOXY CATALYSTS
摘要:
A process for preparing an olefin homopolymer or copolymer comprises contacting ethylene, an alpha-olefin, or a combination, and a catalytic amount of a metal-ligand complex catalyst of a particular formula that requires at least one halogen atom that is ortho to a bridging moiety. The strategic location of the halogen atom(s) ensures a product having a molecular weight that is predictably and significantly reduced in comparison with that of copolymers produced using otherwise identical metal-ligand complex catalysts that lack halogen atoms at the specified sites.
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