Invention Application
US20160304643A1 PROCESSES TO IMPROVE REACTOR STABILITY FOR THE PREPARATION OF ETHYLENE-BASED POLYMERS USING ASYMMETRICAL POLYENES
有权
使用不对称聚酯制备基于乙烯的聚合物来提高反应器稳定性的方法
- Patent Title: PROCESSES TO IMPROVE REACTOR STABILITY FOR THE PREPARATION OF ETHYLENE-BASED POLYMERS USING ASYMMETRICAL POLYENES
- Patent Title (中): 使用不对称聚酯制备基于乙烯的聚合物来提高反应器稳定性的方法
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Application No.: US15101347Application Date: 2014-12-23
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Publication No.: US20160304643A1Publication Date: 2016-10-20
- Inventor: Christopher R. Eddy , John O. Osby , Sean W. Ewart , Sarat Munjal , Stefan Hinrichs , Otto J. Berbee
- Applicant: DOW GLOBAL TECHNOLOGIES LLC
- International Application: PCT/US2014/072214 WO 20141223
- Main IPC: C08F210/02
- IPC: C08F210/02

Abstract:
The invention provides a process to form an ethylene-based polymer, said process comprising polymerizing ethylene and at least one asymmetrical polyene, comprising an “alpha, beta unsaturated—carbonyl end” and a “C—C double bond end,” and wherein the polymerization takes place in the presence of at least one free-radical initiator, and wherein the polymerization takes place in a reactor configuration comprising at least two reaction zones, reaction zone 1 and reaction zone i (i≧2), wherein reaction zone i is downstream from reaction zone 1; and wherein at least one chain transfer agent (CTA) is added to the polymerization, and wherein the CTA is a saturated hydrocarbon or an unsaturated hydrocarbon.
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