Invention Application
- Patent Title: SYNTHESIS OF (METH) ACRYLIC ANHYDRIDE BY TRANSANHYDRIZATION
- Patent Title (中): (甲基)丙烯酸酐通过过渡化合物的合成
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Application No.: US15111258Application Date: 2015-01-20
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Publication No.: US20160332949A1Publication Date: 2016-11-17
- Inventor: Pierre ARDAUD , Thierry VIDAL , Rabih RACHED
- Applicant: RHODIA OPERATIONS
- Priority: FR14/00106 20140120
- International Application: PCT/EP2015/050972 WO 20150120
- Main IPC: C07C51/573
- IPC: C07C51/573 ; C07C51/56

Abstract:
The invention relates to a method for producing a (meth)acrylic anhydride A-C(═O)—O—(O═)C-A, comprising the following steps: a) a step of reacting an anhydride B—C(═O)—O—(O═)C—B with an acid A-COOH, resulting in the formation of mixed anhydride A-C(═O)—O—(O═)C—B and acid B—COOH; and b) a step of reacting the mixed anhydride with A-COOH, resulting in the (meth)acrylic anhydride. According to the invention, reaction steps (a) and (b) are carried out in the presence of hydrated triflic acid, and the anhydride A-C(═O)—O—(O═)C-A is isolated from the reaction medium produced in step (b) as follows: e1) heavy compounds having a volatility less than or equal to that of the anhydride A-C(═O)—O—(O═)C-A are separated from the reaction medium, said compounds including the anhydride and the hydrated triflic acid; e2) the anhydride is separated from the heavy compounds by difference in volatility.
Public/Granted literature
- US09969670B2 Synthesis of (meth) acrylic anhydride by transanhydrization Public/Granted day:2018-05-15
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