Invention Application
US20160332949A1 SYNTHESIS OF (METH) ACRYLIC ANHYDRIDE BY TRANSANHYDRIZATION 有权
(甲基)丙烯酸酐通过过渡化合物的合成

  • Patent Title: SYNTHESIS OF (METH) ACRYLIC ANHYDRIDE BY TRANSANHYDRIZATION
  • Patent Title (中): (甲基)丙烯酸酐通过过渡化合物的合成
  • Application No.: US15111258
    Application Date: 2015-01-20
  • Publication No.: US20160332949A1
    Publication Date: 2016-11-17
  • Inventor: Pierre ARDAUDThierry VIDALRabih RACHED
  • Applicant: RHODIA OPERATIONS
  • Priority: FR14/00106 20140120
  • International Application: PCT/EP2015/050972 WO 20150120
  • Main IPC: C07C51/573
  • IPC: C07C51/573 C07C51/56
SYNTHESIS OF (METH) ACRYLIC ANHYDRIDE BY TRANSANHYDRIZATION
Abstract:
The invention relates to a method for producing a (meth)acrylic anhydride A-C(═O)—O—(O═)C-A, comprising the following steps: a) a step of reacting an anhydride B—C(═O)—O—(O═)C—B with an acid A-COOH, resulting in the formation of mixed anhydride A-C(═O)—O—(O═)C—B and acid B—COOH; and b) a step of reacting the mixed anhydride with A-COOH, resulting in the (meth)acrylic anhydride. According to the invention, reaction steps (a) and (b) are carried out in the presence of hydrated triflic acid, and the anhydride A-C(═O)—O—(O═)C-A is isolated from the reaction medium produced in step (b) as follows: e1) heavy compounds having a volatility less than or equal to that of the anhydride A-C(═O)—O—(O═)C-A are separated from the reaction medium, said compounds including the anhydride and the hydrated triflic acid; e2) the anhydride is separated from the heavy compounds by difference in volatility.
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