The disclosure provides for an article including a substrate, an environmental barrier coating (EBC), a bondcoat and a boron source. The substrate may include a silicon-including ceramic material. The EBC may be disposed over the substrate, and the bondcoat may disposed between the substrate and the EBC. The bondcoat may include silicon. The boron source may be disposed within the article to provide an effective amount of boron to form an oxide including silicon and at least 0.1 weight percent boron during exposure of the bondcoat to an oxidizing environment at a temperature greater than 900 degrees Celsius. The oxide may be a borosilicate glass that is substantially devitrification resistant to prevent spallation of the EBC and thereby enhance the temperature capability of the article.