The invention relates to a method for producing an adhesive bond by means of an adhesive, wherein a composition containing at least a substance reactive in a radical polyreaction and a catalytically active substance is used as the adhesive, wherein at least one metal complex from the group of the metal phthalocyanines and/or from the group of the metal porphyrins is selected as the catalytically active substance, wherein a polyreaction of the reactive substance occurs, which polyreaction is initiated by the application of a plasma.