- 专利标题: CATALYST COMPOSITION AND A PROCESS FOR MAKING ULTRA HIGH MOLECULAR WEIGHT POLY (ALPHA-OLEFIN) DRAG REDUCING AGENTS
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申请号: US15349351申请日: 2016-11-11
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公开(公告)号: US20170145130A1公开(公告)日: 2017-05-25
- 发明人: Muhammad Atiqullah , Abdel Salam Al-Sarkhi , Faisal Mohammed Al-Thenayan , Abdullah Raddad Al-Malki , Wei Xu , Anwar Hossaen
- 申请人: Saudi Arabian Oil Company , King Fahd University of Petroleum & Minerals
- 申请人地址: SA Dhahran SA Dhahran
- 专利权人: Saudi Arabian Oil Company,King Fahd University of Petroleum & Minerals
- 当前专利权人: Saudi Arabian Oil Company,King Fahd University of Petroleum & Minerals
- 当前专利权人地址: SA Dhahran SA Dhahran
- 主分类号: C08F210/14
- IPC分类号: C08F210/14 ; F17D3/12 ; F17D1/16
摘要:
A method of producing ultra high molecular weight (UHMW) C4-C30 α-olefin drag reducing agent (DRA). The method includes polymerizing in a reactor a first α-olefin monomer in the presence of catalyst and hydrocarbon solvent to produce the DRA. The catalyst consists essentially of at least one tertiary monophenyl amine having a formula R1R2N-aryl, where R1 and R2 are the same or different, and each is a hydrogen, an alkyl, or a cycloalkyl group, where at least one of R1 and R2 contain at least one carbon atom; at least one titanium halide having a formula TiXm, where m is from 2.5 to 4.0 and X is a halogen containing moiety; and at least one cocatalyst having a formula AlRnY3-n where R is a hydrocarbon radical, Y is a halogen or hydrogen, and n is 1-20. Further, the catalyst is absent of a carrier or support.
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