- 专利标题: METHOD AND APPARATUS FOR PRODUCING DICYANOBENZENE
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申请号: US15025812申请日: 2015-03-09
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公开(公告)号: US20170217873A1公开(公告)日: 2017-08-03
- 发明人: Yukiya IBI , Tatsuyuki KUMANO , Natsumi WAKITA
- 申请人: MITSUBISHI GAS CHEMICAL COMPANY, INC.
- 申请人地址: JP Chiyoda-ku, Tokyo
- 专利权人: MITSUBISHI GAS CHEMICAL COMPANY, INC.
- 当前专利权人: MITSUBISHI GAS CHEMICAL COMPANY, INC.
- 当前专利权人地址: JP Chiyoda-ku, Tokyo
- 优先权: JP2014-046426 20140310
- 国际申请: PCT/JP2015/056776 WO 20150309
- 主分类号: C07C209/48
- IPC分类号: C07C209/48 ; C07C253/28 ; B01D53/14 ; B01D3/14 ; B01D17/02 ; B01D19/00 ; B01D1/00 ; C07C253/34 ; B01D11/04
摘要:
The object is to prevent deterioration and loss of dicyanobenzene in producing dicyanobenzene by ammoxidation of xylene to thereby achieve industrial and economical advantage in producing of dicyanobenzene. The method for producing dicyanobenzene of the present invention includes: contacting a xylene-ammoxidation reaction gas containing dicyanobenzene in ammoxidation of xylene with an organic solvent so as to obtain a dicyanobenzene-absorbing solution; contacting the dicyanobenzene-absorbing solution with a basic aqueous solution containing a salt such as ammonium carbonate so as to extract a water-soluble salt formed by neutralization reaction between carboxylic acid in the dicyanobenzene-absorbing solution and a base in the basic aqueous solution into an aqueous phase; separating the mixture of the dicyanobenzene-absorbing solution and the basic aqueous solution into an organic phase and an aqueous phase; decomposing the salt such as ammonium carbonate contained in the organic phase for separation of the salt from the organic phase; and distilling the organic phase to separate low boiling point compounds contained in the organic phase from the organic phase so as to obtain dicyanobenzene.
公开/授权文献
- US09822062B2 Method and apparatus for producing dicyanobenzene 公开/授权日:2017-11-21
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