A door bolt structure of an electronic device includes a door frame, a door panel, and a resilient metallic wire. The door panel is movably disposed at the door frame and provides a hermetic seal to the door frame. The two ends of the resilient metallic wire are connected to the door panel. The resilient metallic wire bends to form hook portions which protrude from the edge of the door panel. When the door panel provides a hermetic seal for the door frame, the hook portions are engaged with an inner edge of the door frame. When pulled, the resilient metallic wire drives the hook portions to separate from the door frame, thereby allowing the door panel to move relative to the door frame.