• 专利标题: METHOD FOR PRODUCING ACETIC ACID
  • 申请号: US15542610
    申请日: 2017-05-25
  • 公开(公告)号: US20180258021A1
    公开(公告)日: 2018-09-13
  • 发明人: Masahiko SHIMIZU
  • 申请人: DAICEL CORPORATION
  • 申请人地址: JP Osaka-shi, Osaka
  • 专利权人: DAICEL CORPORATION
  • 当前专利权人: DAICEL CORPORATION
  • 当前专利权人地址: JP Osaka-shi, Osaka
  • 优先权: JP2017-044342 20170308
  • 国际申请: PCT/JP2017/019577 WO 20170525
  • 主分类号: C07C51/12
  • IPC分类号: C07C51/12 C07C51/44
METHOD FOR PRODUCING ACETIC ACID
摘要:
It is intended to provide a method capable of industrially and efficiently producing acetic acid having a good potassium permanganate test value without a large cost.A method for producing acetic acid according to the present invention is a method for producing acetic acid comprising: a carbonylation reaction step; an evaporation step; a lower boiling point component removal step; and a first overhead stream recycle step of recycling at least a portion of an aqueous phase and/or an organic phase obtained by condensing a first overhead stream obtained in the lower boiling point component removal step to a reaction vessel, wherein a crotonaldehyde concentration in a first acetic acid stream obtained in the lower boiling point component removal step is controlled to not more than 2.2 ppm by mass. The catalyst system may further contain an ionic iodide. The method for producing acetic acid may further comprise an acetaldehyde separation and removal step of distilling at least a portion of the aqueous phase and/or the organic phase obtained by condensing the first overhead stream to separate and remove acetaldehyde.
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