- 专利标题: METHOD FOR PRODUCING ACETIC ACID
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申请号: US15542855申请日: 2017-05-25
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公开(公告)号: US20180282253A1公开(公告)日: 2018-10-04
- 发明人: Masahiko SHIMIZU
- 申请人: DAICEL CORPORATION
- 申请人地址: JP Osaka-shi, Osaka
- 专利权人: DAICEL CORPORATION
- 当前专利权人: DAICEL CORPORATION
- 当前专利权人地址: JP Osaka-shi, Osaka
- 优先权: JP2017-062764 20170328
- 国际申请: PCT/JP2017/019579 WO 20170525
- 主分类号: C07C51/12
- IPC分类号: C07C51/12 ; C07C51/44 ; B01D3/14 ; B01D3/00
摘要:
There is provided a method allowing industrially efficient production of high quality acetic acid having a good potassium permanganate test value and a low impurity content without a large cost.The method for producing acetic acid according to the present invention has a carbonylation reaction step, an evaporation step and a lower boiling point component removal step, and wherein with heating of the evaporator, (i) an acetaldehyde concentration in the aqueous phase of an overhead condensate in a lower boiling point component removal column is controlled to not less than 2340 ppm by mass; and/or (ii) a methyl acetate concentration in the aqueous phase is controlled to less than 19.0% by mass and/or; (iii) a methyl acetate concentration in the organic phase of the overhead condensate in the lower boiling point component removal column is controlled to less than 38.0% by mass, and then at least a portion of the aqueous phase is treated in the acetaldehyde separation and removal step to recycle a residual liquid after the acetaldehyde separation and removal to the reaction vessel and/or the acetaldehyde separation and removal step and/or other processes.
公开/授权文献
- US10308581B2 Method for producing acetic acid 公开/授权日:2019-06-04