Invention Application
- Patent Title: METHODS OF PRODUCING HIERARCHICAL BETA ZEOLITES WITH TUNABLE MESOPOROSITY THROUGH PORE DIRECTING AGENT ASSISTED BASE LEACHING
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Application No.: US15583380Application Date: 2017-05-01
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Publication No.: US20180311652A1Publication Date: 2018-11-01
- Inventor: Ke Zhang , Sergio Fernandez
- Applicant: Saudi Arabian Oil Company
- Applicant Address: SA Dhahran
- Assignee: Saudi Arabian Oil Company
- Current Assignee: Saudi Arabian Oil Company
- Current Assignee Address: SA Dhahran
- Main IPC: B01J29/70
- IPC: B01J29/70 ; B01J35/10 ; B01J37/00 ; B01J37/04 ; C01B39/48 ; C01B39/02 ; C07C5/25

Abstract:
Methods for producing mesoporous beta zeolites from parent beta zeolites having a Si/Al molar ratio of at least 10 comprise selecting a target average mesoporous size between 2 nm and 8 nm for the parent beta zeolites, selecting a pore directing agent (PDA) based on the target average mesopore size, where a non-ionic surfactant, a small cationic surfactant has a molecular weight of greater than 100 grams/mole, or both may be selected as the PDA when the target average mesopore size is at least 5 nm, and a large cationic surfactant having a molecular weight of less than 100 grams/mole may be selected as the PDA when the target average mesopore size is less than 5 nm. The method further comprises adding the selected PDA to an alkaline solution to form a PDA-base mixture, and adding the parent beta zeolites to the PDA-base mixture to produce the mesoporous beta zeolites.
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