The present invention discloses a fluorescence enhancing gel-film and the manufacture method thereof. The aforementioned fluorescence enhancing gel-film comprises a frame-gel and a nano-scale spherical cavity structure. The frame-gel is in a form of a film. The nano-scale spherical cavity structure which is distributed in a periodic or non-periodic arrangement is disposed in the frame-gel. The fluorescence enhancing gel-film is able to improve the emitting performance and efficiency of a light emitting device significantly.