An on-vehicle structure of a power converter includes a housing of the power converter mounted on a vehicle, a structure mounted on the vehicle, and a high-voltage connector attached to the housing. The high-voltage connector is configured to apply a voltage exceeding a predetermined threshold voltage, the high-voltage connector is positioned between the housing and the structure such that the high-voltage connector faces the structure in a removal direction of the high-voltage connector when the high-voltage connector is attached to the housing, and in a state where the high-voltage connector is attached to the housing, a length of a portion of the high-voltage connector embedded in the housing is determined so as to be longer than a distance between the high-voltage connector and the structure.