发明申请
- 专利标题: Production Method of Semi-Aromatic Polyamide, and Semi-Aromatic Polyamide
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申请号: US15779414申请日: 2017-06-29
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公开(公告)号: US20200055985A1公开(公告)日: 2020-02-20
- 发明人: Zhirong Chen , Hong Yin , Qin Zhang , Xiaoxiao Wu , Wengang Hong , Hangjun Deng , Guiyang Zhou , Changze Wang
- 申请人: ZHEJIANG NHU SPECIAL MATERIALS CO., LTD. , Zhejiang University , ZHEJIANG NHU COMPANY LTD.
- 优先权: CN201611239093.9 20161228
- 国际申请: PCT/CN2017/090830 WO 20170629
- 主分类号: C08G69/28
- IPC分类号: C08G69/28 ; C08G69/26 ; C08L77/08
摘要:
The present disclosure provides a production method of a semi-aromatic polyamide, and a semi-aromatic polyamide. Said production method of a semi-aromatic polyamide includes: step 1 of subjecting an initial charge of a diamine and a binary acid in an amine/acid molar ratio of less than 1.0 to form a slurry together with water and a catalyst, and subjecting the slurry to heating and dissolution to form a saline solution; step 2 of dehydrating said saline solution after detecting the composition thereof, detecting the content of diamine in a steam condensate from a dehydration unit, adjusting the amine/acid molar ratio to be larger than 1.0 by a molten diamine and a monoacid as a molecular weight regulator, and performing pre-polymerization; and step 3 of subjecting a pre-polymerization solution to post-polycondensation after vacuum flashing. The semi-aromatic polyamide of the present disclosure has a low gel content, excellent performance and extensive scope of application.
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