An electrostatic separation device (is for a mixture of granules of different materials. The device includes a separation chamber having an inlet and delimiting an inner volume and a collection device for granules placed in the inner volume, opposite the inlet. At least two pairs of electrodes are successively placed in the elevation direction in the inner volume, between the inlet and the collection device. Each pair includes an anode and a cathode, placed on either side of a central axis extending in the elevation direction. At least one generating system is suitable for applying a difference in electric potential between the anode and the cathode of each pair.