Invention Application
- Patent Title: THERMOELECTRIC CONVERSION MATERIAL, THERMOELECTRIC CONVERSION MODULE, AND METHOD FOR MANUFACTURING THERMOELECTRIC CONVERSION MATERIAL
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Application No.: US16962461Application Date: 2019-01-15
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Publication No.: US20210074898A1Publication Date: 2021-03-11
- Inventor: Takeshi SHIMADA , Nan WANG , Michiko MATSUDA
- Applicant: HITACHI METALS, LTD.
- Applicant Address: JP Tokyo
- Assignee: HITACHI METALS, LTD.
- Current Assignee: HITACHI METALS, LTD.
- Current Assignee Address: JP Tokyo
- Priority: JP2018-004538 20180115
- International Application: PCT/JP2019/000945 WO 20190115
- Main IPC: H01L35/18
- IPC: H01L35/18 ; H01L35/32 ; H01L35/34 ; C01G51/00 ; C22C12/00 ; B22F3/10 ; B22F9/04

Abstract:
A thermoelectric conversion material having a high dimensionless figure of merit ZT includes: a large number of polycrystalline grains which include a skutterudite-type crystal structure containing Yb, Co, and Sb; and an intergranular layer which is between the neighboring polycrystalline grains and includes crystals in which an atomic ratio of O to Yb is more than 0.4 and less than 1.5. A method for manufacturing a thermoelectric conversion material includes: a weighing step; a mixing step; a ribbon preparation step by rapidly cooling and solidifying a melt of the raw materials by using a rapid liquid cooling solidifying method; a first heat treatment step including heat treating in an inert atmosphere with an adjusted oxygen concentration; a second heat treatment step including heat treating in a reducing atmosphere; and manufacturing the thermoelectric conversion material by a pressure sintering step in an inert atmosphere.
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