发明申请
- 专利标题: CATALYSTS
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申请号: US17253770申请日: 2019-06-28
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公开(公告)号: US20210292355A1公开(公告)日: 2021-09-23
- 发明人: Noureddine AJELLAL , Ville VIRKKUNEN , Luigi Maria Cristoforo RESCONI , Vyatcheslav V. IZMER , Dmitry S. KONONOVICH , Alexander Z. VOSKOBOYNIKOV , Jingbo WANG , Simon SCHWARZENBERGER , Wilfried Peter TÖLTSCH
- 申请人: BOREALIS AG
- 申请人地址: AT Vienna
- 专利权人: BOREALIS AG
- 当前专利权人: BOREALIS AG
- 当前专利权人地址: AT Vienna
- 优先权: EP18180469.1 20180628
- 国际申请: PCT/EP2019/067435 WO 20190628
- 主分类号: C07F17/00
- IPC分类号: C07F17/00 ; C08F110/06 ; C08F4/659
摘要:
A complex of formula (I): (I′) M is Hf; each X is a sigma ligand; L is a bridge of formula -(ER82)y—; y is 1 or 2; E is C or Si; each R8 is independently a C1-C20-hydrocarbyl, tri(C1-C20-alkyl)silyl, C6-C20- aryl, C7-C20-arylalkyl or C7-C20-alkylaryl or L is an alkylene group such as methylene or ethylene; Ar and Ar′ are each independently an aryl or heteroaryl group optionally substituted by 1 to 3 groups R1 or R1′ respectively; R1 and R1′ are each independently the same or can be different and are a linear or branched C1-C6-alkyl group, C7-20 arylalkyl, C7-20 alkylaryl group or C6-20 aryl group with the proviso that if there are four or more R1 and R1′ groups present in total, one or more of R1 and R1′ is other than tert butyl; R2 and R2′ are the same or are different and are a CH2—R9 group, with R9 being H or linear or branched C1-C6-alkyl group, C3-8 cycloalkyl group, C6-10 aryl group; each R is a —CH2—, —CHRx- or C(Rx)2-group wherein Rx is C1-4 alkyl and where m is 2-6; R5 is a linear or branched C1-C6-alkyl group, C7-20 arylalkyl, C7-20 alkylaryl group or C6-C20-aryl group; R6 is a C(R10)3 group, with R10 being a linear or branched C1-C6 alkyl group; and R6 and R7′ are the same or are different and are H or a linear or branched C1-C6-alkyl group. Invention relates also to a catalyst in solid form comprising (i) a complex of formula (I) and (ii) a cocatalyst of an aluminium compound and (iii) a cocatalyst of a boron compound.