A method for purifying sodium bromide by the waste circuit board pyrolysis coke, belonging to the field of purifying sodium bromide and high-value utilization, and more particularly, relating to a method for reducing and purifying crude bromine salt enriched from waste circuit board smelting ash by using waste circuit boards pyrolysis coke. The main steps are as follows: carbonization conversion, purification filtration and vacuum exsolution. The pure sodium bromide crystal was obtained by reducing crude bromine salt enriched from waste circuit board smelting ash by using coke in waste circuit board pyrolysis residues, realizing the resource coupling and high-value utilization of the two wastes, avoiding the secondary pollution in the process of recycling the waste circuit boards. It has the characteristics of simple operation, high resource utilization rate and no tail liquid discharge.