To provide a piston ring for an internal combustion engine, particularly a second compression ring, which has excellent wear resistance and can achieve both lower fuel consumption and efficient combustion. The above-described problem is solved by a piston ring (1) for an internal combustion engine formed so as to have a tapered shape by a peripheral surface (14) that gradually projects outward from a top to a bottom, and a radial cross-sectional shape of a Napier ring. The peripheral surface (14) is constituted by an outer edge end portion (14b) that has a non-tapered shape and comes into sliding contact, as a peripheral sliding surface, with a mating material, an outer peripheral tapered part (14a) formed at a predetermined taper angle (α) above the outer edge end portion (14b), a curved surface part (14c) having a diameter that gradually decreases inward from the outer edge end portion (14b) to a lower end in an axial direction, and a lower end portion (14d) forming a section of the curved surface part (14c). A distance (d2) between a position (A) of the outer edge end portion (14b) and a position (C) of the lower end portion (14d) in a ring axial direction is within a range of 0.001 mm to 0.05 mm, and a contact width (d1) of the outer edge end portion (14b) in the ring axial direction is within a range of 0.01 mm to 0.3 mm.