The present disclosure provides a light-adjusting glass and a manufacturing method thereof, and a glass assembly, and belongs to the field of display glass technology. The light-adjusting glass of the present disclosure includes at least one light-adjusting module; the light-adjusting module includes a first substrate and a second substrate opposite to each other, and a dye liquid crystal layer between the first substrate and the second substrate; wherein liquid crystal molecules in the dye liquid crystal layer deflect under a control of an electric field between the first substrate and the second substrate, to control a transmittance of light; wherein the dye liquid crystal layer includes a polymer network, which is configured such that when the electric field between the first substrate and the second substrate changes, twisting degrees of the liquid crystal molecules are identical, and twisting degrees of dye molecules are identical.