This application provides a lithium metal battery, and relates to the battery field. The lithium metal battery includes a positive electrode, a negative electrode, a separator disposed between the positive electrode and the negative electrode, and an electrolytic solution infiltrating the separator. The negative electrode includes a negative electrode current collector and a lithium-aluminum alloy layer disposed on at least one surface of the negative electrode current collector; and the electrolytic solution includes an electrolyte and a solvent, where the solvent contains a film-forming agent, and the film-forming agent is FEC and/or DFEC.