Disclosed are a gas detection intelligence training system and an operating method thereof. The gas detection intelligence training system includes a mixing gas measuring device that collects an environmental gas from a surrounding environment, generates a mixing gas based on the collected environmental gas and a target gas, senses the mixing gas by using a first sensor array and a second sensor array under a first sensing condition and a second sensing condition, respectively, and generates measurement data based on the sensed results of the first sensor array and the second sensor array, and a detection intelligence training device including a processor that generates an ensemble prediction model based on the measurement data.