An electronic device is provided. The electronic device includes a processor connected to a first SIM and a second SIM, and RF devices used for communication based on the first SIM and on the second SIM, the processor identifies expiration of a timer for paging monitoring associated with the second SIM while use of the RF devices is allocated to the first SIM, to allocate use of the RF devices to the second SIM to perform first paging monitoring and first-type measurement, reallocates use of the RF devices to the first SIM according to completion of the first paging monitoring and the first-type measurement, identifies expiration of the timer for the paging monitoring associated with the second SIM while use of the RF devices is reallocated to the first SIM, and allocates use of the RF devices to the second SIM to perform second paging monitoring and second-type measurement.